Assembly of luminescent Ag(I) coordination architectures adjusted by modification of pyrimidine-based thioether ligands

Three novel luminescent coordination architectures: discrete metallomacrocycle [Ag4(L2)2(NO3)4] · 2MeOH (3), 1D chain {[Ag2L3(NO3)2] · 2CCl3}n (4) and 2D wire netlike structure {[AgL3(DMF)]ClO4 · 0.25H2O}n (5), have been designed and synthesized by modification of pyrimidine-based thioether ligands.