کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1316566 | 1499444 | 2015 | 23 صفحه PDF | دانلود رایگان |
• Design of bioinspired hydrogenase active site models as catalysts for proton reduction.
• Importance of designing proton reduction catalysts lies in the development of a sustainable hydrogen economy.
• The review focuses on aromatic dithiolate-bridged mono-, di- and polynuclear iron carbonyl complexes.
• Comparisons with alkyl-dithiolate bridged complexes have been made where relevant.
The design, syntheses and characteristics of metal carbonyl complexes with aromatic dithiolate linkers reported as bioinspired hydrogenase catalytic site models are described and reviewed. Among these the complexes capable of hydrogen generation have been discussed in detail. Comparisons have been made with carbonyl complexes having alkyl dithiolates as linkers between metal centers.
Aromatic dithiolate-bridged carbonyl complexes reported to date as hydrogenase active site models have been discussed and comparisons have been made with the alkyl dithiolate-bridged complexes.Figure optionsDownload as PowerPoint slide
Journal: Journal of Inorganic Biochemistry - Volume 143, February 2015, Pages 88–110