کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1316917 | 976491 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Catalytic oxidation of cyclohexane by a binuclear Fe(III) complex biomimetic to methane monooxygenase
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel binuclear Fe(III) complex [Fe(III)(BPMP)Cl(μ-O)Fe(III)Cl3] (1) was prepared from the reaction between (bis(2-pyridylmethyl)-1,4-piperazine) and [Fe(OH2)6]Cl3, in acetonitrile. The title compound was characterized by spectroscopic, electrochemical and X-ray crystallography analysis. The catalytic activity of the complex was evaluated through cyclohexane oxidation, using hydrogen peroxide as the terminal oxidant. Reaction products were identified by gas chromatography. Conversions up to 19.2% were observed (12.6% and 6.6% yields for cyclohexanol and cyclohexanone, respectively). The catalytic activity exhibited by 1 suggests that it can be considered as a functional biomimetic analog to methane monooxygenase.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Inorganic Biochemistry - Volume 99, Issue 10, October 2005, Pages 2054–2061
Journal: Journal of Inorganic Biochemistry - Volume 99, Issue 10, October 2005, Pages 2054–2061
نویسندگان
Maria Carolina Esmelindro, Enrique G. Oestreicher, Heiddy Márquez-Alvarez, Cláudio Dariva, Sílvia M.S. Egues, Christiane Fernandes, Adailton J. Bortoluzzi, Valderes Drago, O.A.C. Antunes,