کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1320495 | 1499830 | 2016 | 7 صفحه PDF | دانلود رایگان |
• Synthesis dark-stable and light-sensitive novel manganese complexes.
• Analytical and spectroscopic characterization of novel imidazoline substituted manganese complexes.
• CO-releasing properties of photoCORM complexes.
• DFT/TDDFT analysis of novel manganese complexes with ORCA package program.
Novel manganese(I)carbonyl complexes of the general formula [Mn(CO)3(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-methylbenzyl)imidazoline, N-(3-methylbenzyl)imidazoline, N-(4-methylbenzyl)imidazoline, N-(2,4,6-trimethylbenzyl)imidazoline) were synthesized and characterized by analytical (LC-MS spectrometry and elemental analysis) and spectroscopic (1H NMR, 13C NMR, cosy2D-NMR, infrared) methods. The CO-releasing properties of these complexes were investigated with myoglobin assay. The DFT/TDDFT calculations were made by ORCA package program with both BP86 and B3LYP functionals.
Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volumes 815–816, 1 August 2016, Pages 16–22