کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1320500 | 1499830 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Substrate-assisted rhodium-catalyzed CH bond cyanation of 2-arylbenzothiazoles
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
• CH Bond cyanation of 2-arylbenzothiazoles.
• Broad functional groups tolerance with moderate to excellent yields.
• Regioselective cyanation was in favor of the less sterically hindered position.
• Cyanated products show potent biological activity.
A mild and efficient substrate-assisted CH bond cyanation of 2-arylbenzothiazoles has been developed using CuCN as cyano-group source. The reaction exhibits broad functional groups tolerance giving the desired products in moderate to excellent yields. Regioselective cyanation was in favor of the less sterically hindered position to those meta-substituted substrate.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volumes 815–816, 1 August 2016, Pages 59–64
Journal: Journal of Organometallic Chemistry - Volumes 815–816, 1 August 2016, Pages 59–64
نویسندگان
Yuanyuan Ping, Qiuping Ding, Zhaobin Chen, Yiyuan Peng,