کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1321284 | 1499888 | 2014 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: (Thio)phosphoryl-functionalized enaminoketones: Synthesis, structure, and complexing properties towards transition metal ions (Thio)phosphoryl-functionalized enaminoketones: Synthesis, structure, and complexing properties towards transition metal ions](/preview/png/1321284.png)
• Condensation of (thio)phosphorylanilines with PhC(O)CHCHONa afforded novel ligands.
• P(X)-functionalized enaminoketones (X = O, S) show interesting structural behavior.
• The ligands obtained readily form κ3-X,N,O-complexes (X = O, S) with transition metals.
P(X)-functionalized enaminoketones (X = O, S) 1a,b have been readily obtained by the condensation of o-(thio)phosphorylated anilines with sodium salt of benzoylacetaldehyde. The ligands derived exist in solution in the expected ketamino tautomeric form, but, unlike typical enaminoketones, tend to exist as cis-isomers in polar media, favored by the formation of the strong PO…HN intramolecular hydrogen bond. This six-membered hydrogen-bonded ring is also observed in the solid structure of 1a, which, nevertheless, features a trans-configuration of the enaminoketone fragment. Independent from the isomeric composition, the ligands obtained readily form κ3-X,N,O (X = O, S) complexes with a range of transition metal ions (Re(I), Pd(II), Cu(II), and Ni(II)) adopting in all cases the cis-configuration. The structures of the novel compounds are confirmed using multinuclear NMR and IR spectroscopy as well as X-ray crystallography.
P(X)-modified enaminoketones as novel ligands.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 752, 15 February 2014, Pages 183–190