Nickel-catalyzed phosphorylation of aryl triflates with P(O)H compounds

• Efficient phosphorylation of aryl triflates with PH compounds.
• Ni-catalysis replaces Pd-catalysis.
• Both > PV(O)H and >PIIIH compounds can be used as the substrate.
• High functional group tolerance.

A nickel-catalyzed phosphorylation of aryl triflates with P(O)H compounds is disclosed. This reaction can proceed smoothly under a mild reaction condition, producing the corresponding aryl phosphorus compounds in good to high yields.

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