کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1321672 | 1499828 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Asymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Asymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexes Asymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexes](/preview/png/1321672.png)
چکیده انگلیسی
• Ru(II), Rh(I) and Ir(III) complexes of C2-symmetric ferrocenyl based chiral bis(phoshinite) ligands have been synthesized.
• The complexes were applied in ATH of alkyl/aryl or alkyl methyl ketones using iso-propanol as the hydrogen source.
• Up to 99% conversion and 98% ee were achieved with these catalytic systems.
Known Ru(II), Rh(I) and Ir(III) complexes of C2-symmetric ferrocenyl based chiral bis(phoshinite) ligands were catalyzed the asymmetric transfer hydrogenation of alkyl/aryl or alkyl methyl ketones. Corresponding secondary alcohols were obtained with high enantioselectivities up to 98% ee and reactivities using iso-propanol as the hydrogen source.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 818, 1 September 2016, Pages 92–97
Journal: Journal of Organometallic Chemistry - Volume 818, 1 September 2016, Pages 92–97
نویسندگان
Feyyaz Durap, Duygu Elma Karakaş, Bünyamin Ak, Akin Baysal, Murat Aydemir,