کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1322071 | 1499925 | 2012 | 8 صفحه PDF | دانلود رایگان |

At 0 °C, photolysis of a hexane solution containing Fe(CO)5 and 2-(phenylethynyl)benzaldehyde (1) affords a mixture of mononuclear (tricarbonyliron-2-phenylindenone, (2) and binuclear acetylene coupled iron carbonyl complexes [Fe(CO)3{η4-2,4–(C6H4CHO)2–3,5-(C6H5)2C4}Fe(CO)3], 3, [Fe(CO)3{ η4-2-(η1–C6H4CHO)–4–(C6H4CHO)–3,5-(C6H5)2C4}Fe(CO)2], 4 and [Fe(CO)3{ η4-4-(η1-2–C6H4CHO)–2–(C6H4CHO)–3,5-(C6H5)2 C4}Fe(CO)2], 5. In compounds 4 and 5, the exocyclic iron atom is η4-bonded with the ferracyclopentadiene unit, and it bears two terminal carbonyls. Its 18 electron count is completed by virtue of the aldehydic oxygen atom coordinating to the iron atom. Photolysis of 2-(ferrocenylethynyl)benzaldehyde (6) under similar condition leads to the formation of tricarbonyliron-2-ferrocenylindenone (7) and tetracarbonyl(2-ferrocenyl-3-(2-formylphenyl)maleoyl)iron (8) predominantly.
Photolysis of a hexane solution of 2-(phenylethynyl)benzaldehyde and Fe(CO)5 at 0 °C results in a mixture of mononuclear (tricarbonyliron-2-phenylindenone) and binuclear ironcarbonyl complexes. Interestingly, in some of the binuclear complexes one of the aldehydic oxygen atoms is coordinated to the exocyclic iron.Figure optionsDownload as PowerPoint slideHighlights
► Synthesis of phenyl and ferrocenyl substituted tricarbonylironindenone complexes.
► Formation of chelated ironcarbonyl complexes.
► Conversion of tricarbonylironindenone complexes to respective indenones.
► Phenyl substituted reactant prefer intermolecular coupling.
Journal: Journal of Organometallic Chemistry - Volume 712, 1 August 2012, Pages 7–14