کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1322226 | 1499867 | 2015 | 6 صفحه PDF | دانلود رایگان |
• Ligands can be obtained in high yields (up to 90%) and regioselectivity up to 100%.
• The enantioselectivity was higher with more bulky subustituent group presence.
• Ligands gave up to 92% yield and 95% ee for the alkynylation of aldehydes.
Several C3-symmetric trialkanolamines can be efficiently obtained via molecular sieve-assisted epoxide ring opening with ammonia in high yields (up to 90%) and regioselectivity up to 100%. These trialkanolamines were effective for the asymmetric alkynylation of aldehydes and the propargyl alcohols were obtained in high yields (up to 92%) and high enantiomeric excesses (up to 95%). The 1H NMR spectra support that there could be a complex mixture of polynuclear Ti(IV)-based species form from the interaction of Ti(IV) with ligand.
Several C3-symmetric trialkanolamines was very effective for the asymmetric alkynylation of aldehydes and the propargyl alcohols were obtained in high yields (up to 92%) and high enantiomeric excesses (up to 95%).Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 775, 1 January 2015, Pages 88–93