کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1322296 | 977194 | 2011 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Dinuclear rhenium(I) carbonyl complexes based on π-conjugated polypyridyl ligands with tetrathiafulvalenes: Syntheses, crystal structures, properties and DFT calculations Dinuclear rhenium(I) carbonyl complexes based on π-conjugated polypyridyl ligands with tetrathiafulvalenes: Syntheses, crystal structures, properties and DFT calculations](/preview/png/1322296.png)
A series of tetrathiafulvalene-substituted 2,3-di(2-pyridyl)quinoxaline (dpq) ligands, 2-(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)-6,7-di(pyridin-2-yl)- [1,3]dithiolo[4,5-g]quinoxaline (L1), dimethyl-2-(6,7-di(pyridin-2-yl)-[1,3]dithiolo[4,5-g]quinoxalin-2-ylidene)-1,3-dithiole-4,5-dicarboxylate (L2), and 2-(5,6-dihydro-[1,3]dithiolo[4,5-b] [1,4]dithiin-2-ylidene)-6,7-di(pyridin-2-yl)-[1,3]dithiolo[4,5-g]quinoxaline (L3), have been prepared. Reactions of these ligands with Re(CO)5Cl afford the corresponding dinuclear rhenium(I) carbonyl complexes, Re2(L)(CO)6Cl2 (L = L1, 5a; L = L2, 5b; L = L3, 5c). All new compounds are fully characterized by 1H NMR, IR and mass spectroscopies. The crystal structures of 5a and 5b have been studied. Optimized conformations and molecular orbital diagrams of 5a−5c have been calculated with density functional theory (DFT). The spin-allowed singlet−singlet electronic transitions of all complexes have been calculated with time-dependent DFT (TDDFT), and the UV–Vis−NIR spectra are discussed based on the theoretical calculations.
A series of tetrathiafulvalene-substituted 2,3-di(2-pyridyl)quinoxaline (dpq) ligands and new dinuclear rhenium carbonyl complexes have been prepared and characterized. The crystal structures of Re2(L)(CO)6Cl2 (L = L1, 5a; L = L2, 5b) have been described. The electrochemical and spectroscopic properties of all complexes have been investigated, and the absorption spectra of 5a−5c have been analyzed by time-dependent density functional theory (TDDFT).Figure optionsDownload as PowerPoint slideHighlights
► Dinuclear rhenium carbonyl complexes with tetrathiafulvalene-substituted 2,3-di(2-pyridyl)quinoxaline ligands are synthesized.
► The luminescence of rhenium(I) complexes from MLCT states is quenched and the NIR fluorescence is observed.
► The absorption spectroscopy is analyzed on the basis of DFT and TDDFT.
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 19, 15 September 2011, Pages 3076–3085