کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1322541 | 1499890 | 2014 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Converting a perimidine derivative to a cationic N-heterocyclic carbene Converting a perimidine derivative to a cationic N-heterocyclic carbene](/preview/png/1322541.png)
• A cationic N-heterocyclic carbene with a sandwich-type backbone is described.
• The reactivity of the cationic carbene is investigated.
• Experimental and DFT work suggest the cationic carbene is a reasonable π-acceptor.
The synthesis and reactivity of the new cationic N-heterocyclic carbene 6 comprising a Cp*Ru+ fragment attached to the aromatic backbone of 1,3-dimethylperimidin-2-ylidene is reported. Carbene 6 forms Rh and Ir complexes of the type [(cod)ClM(6)]+ and [(CO)2ClM(6)]+. The analogous complexes of the neutral perimidin-2-ylidene 9 were prepared for comparison purposes. TEP values for both NHCs were calculated from the IR spectra of the carbonyl complexes. The TEP of the cationic carbene 6 (2062 cm−1) is shifted to higher wavenumbers compared to the neutral derivative 9 (2057 cm−1) indicating that the former ligand is a poorer overall donor. In addition, DFT calculations revealed a reduced HOMO–LUMO gap for the cationic system suggesting an increased π-acceptor character. Crystal structures of the related complexes [IrCl(cod)NHC(L)] with L = 6 and 9 were determined by X-ray diffraction and show only marginal differences in the geometrical parameters.
The cationic N-heterocyclic carbene 1 with an organometallic sandwich-type backbone was prepared and its ligand properties were compared to its neutral analog 2. Experimental and DFT data suggest that 1 is a reasonable π-acceptor in metal complexes. X-ray structures of (COD)IrCl complexes of both ligands were determined.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 750, 15 January 2014, Pages 23–29