کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1322547 1499890 2014 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Dialkylaluminium 2-imidazolylphenolates: Synthesis, characterization and ring-opening polymerization behavior towards lactides
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Dialkylaluminium 2-imidazolylphenolates: Synthesis, characterization and ring-opening polymerization behavior towards lactides
چکیده انگلیسی


• Highly sensitive dialkylaluminium 2-imidazolyl-phenolates.
• Distorted tetrahedral geometry around aluminum.
• The seldom examples of bi-dentate aluminum for high efficiency ROP of lactides.
• T he efficient ROP of lactides initiated by alumoorganic compounds.
• The polylactides with high molecular weights.

The stoichiometric reaction of the 2-imidazolylphenols (L1–L9) with the trialkylaluminium reagents AlR3 (R = Me, Et and iBu), afforded the corresponding dialkylaluminium 2-imidazolylphenolate complexes [R2Al(L1–L9)] (C1–C11), which were characterized by 1H/13C NMR spectroscopy and by elemental analysis. The molecular structures of the representative complexes C1, C2, C4, C6 and C11 were determined by single-crystal X-Ray diffraction, and revealed a distorted tetrahedral geometry at aluminum. These dialkylaluminium 2-imidazolylphenolates (C1–C11) could efficiently catalyze the ring-opening polymerization of lactides to afford high molecular weight polylactide, both in the presence and absence of BnOH, and as such represent rare examples of the use of bi-dentate ligation at aluminum in such lactide polymerization systems. On the basis of the polymerization results for l-lactide, d-lactide and rac-lactide, the nature of the ligands and the aluminum bound alkyls were found to significantly affect the catalytic activity as well as the properties of the resultant polylactides.

Dialkylaluminium 2-imidazolyl-phenolates were synthesized and fully characterized. In both presence and absence of BnOH, all aluminum complexes efficiently catalyze the ring-opening polymerization of lactides producing polylactides of high molecular weights.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 750, 15 January 2014, Pages 65–73
نویسندگان
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