کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1322561 1499890 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical parameterization of 1,1′-disubstituted cobaltocenium compounds
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Electrochemical parameterization of 1,1′-disubstituted cobaltocenium compounds
چکیده انگلیسی


• Electrochemistry of 1,1′-disubstituted cobaltocenium compounds was examined.
• X-ray structures of two new 1,1′-disubstituted cobaltocenium compounds.
• Correlation of redox potentials of cobaltocenium compounds with ferrocene analogs.

Two new 1,1′-disubstituted cobaltocenium compounds, [(C5H4CHEt2)2Co][PF6] and [(C5H4SiMe3)2Co][PF6], were synthesized and the X-ray crystal structures were determined. The electrochemistry of seven 1,1′-disubstituted cobaltocenium compounds and the analogous ferrocene compounds was studied in methylene chloride using cyclic voltammetry. The affect of the various substituents on the redox potentials of these compounds was examined and trends in the electrochemical data were explored.

Electrochemical data for 1,1′-disubstituted cobaltocenium compounds were parameterized and compared to analogous ferrocene compounds. The X-ray crystal structures of two new 1,1′-disubstituted cobaltocenium compounds were determined.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 750, 15 January 2014, Pages 107–111
نویسندگان
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