کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1322603 1499892 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Formation of (E)-[FcC(PS2(OR)2)CH(PS2(OR)2)] (R = Me, Et, iPr) in photolytic reactions of ferrocenylacetylene and [(RO)2PS2H] in hexane/alcohols: Experimental and DFT study
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Formation of (E)-[FcC(PS2(OR)2)CH(PS2(OR)2)] (R = Me, Et, iPr) in photolytic reactions of ferrocenylacetylene and [(RO)2PS2H] in hexane/alcohols: Experimental and DFT study
چکیده انگلیسی


• [(RO)2P(S)S] radicals play an important role in substituted ethene formation.
• Structure of (E)-[FcC(PS2(OMe)2)CH(PS2(OMe)2)] was confirmed by single crystal X-ray analyses.
• Relative stabilities of [(RO)2P(S)S] radicals in polar and non-polar solvents have been studied by DFT calculations.

Photochemical reactions of ferrocenylacetylene with dialkyldithiophosphoric acid in hexane at low temperature led to the formation of (E)-[FcC(PS2(OR)2)CH(PS2(OR)2)] (R = Me, Et, iPr). Formation of these compounds have been studied experimentally and computationally in different solvents.

Photochemical reactions of ferrocenylacetylene with dialkyldithiophosphoric acid in hexane at low temperature led to the formation of (E)-[FcC(PS2(OR)2)CH(PS2(OR)2)] (R = Me, Et, iPr). Formation of these compounds have been studied experimentally and computationally in different solvents.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 748, 15 December 2013, Pages 46–50
نویسندگان
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