کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1322682 | 1499899 | 2013 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preparation of a stable disilane amidinium heterocycle and attempted syntheses of an inorganic N-heterocyclic carbene Preparation of a stable disilane amidinium heterocycle and attempted syntheses of an inorganic N-heterocyclic carbene](/preview/png/1322682.png)
The cyclic disilane amidinium salt [(Me2SiNDipp)2CH]OTf (Dipp = 2,6-iPr2C6H3; OTf = OSO2CF3−) was obtained in high yield, and attempts to generate the N-heterocyclic carbene [(Me2SiNDipp)2C:] via deprotonation with numerous bases exclusively gave ring-opened products of the general form: R–SiMe2–SiMe2N(Dipp)–CHNDipp (R = carbon-, nitrogen- or oxygen-based nucleophiles). Although this approach was not directly successful in generating silicon-based N-heterocyclic carbenes, judicious manipulation of the ring-bound substituents might enable the future synthesis of new inorganic carbenes to transpire.
A cyclic disilicon amidinium salt was obtained in high yield, and attempts to generate an N-heterocyclic carbene via deprotonation with numerous bases exclusively gave ring-opened products.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 739, 1 September 2013, Pages 26–32