کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1322688 | 1499899 | 2013 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex](/preview/png/1322688.png)
• [Cp*IrCl2]2 reacts with a conjugated enyne to form a complex containing a η3-tetraenyl ligand.
• Head-to-head coupling of the alkyne functionality of two enynes.
• Combined experimental and computational study of reaction pathway.
Reaction of the dimeric species [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in C–C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally.
The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in the formation of a complex containing a η3-tetraenyl ligand, resulting from the head-to-head C–C coupling between the alkyne functionalities of two conjugated enyne molecules Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 739, 1 September 2013, Pages 52–56