کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1322688 1499899 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex
چکیده انگلیسی


• [Cp*IrCl2]2 reacts with a conjugated enyne to form a complex containing a η3-tetraenyl ligand.
• Head-to-head coupling of the alkyne functionality of two enynes.
• Combined experimental and computational study of reaction pathway.

Reaction of the dimeric species [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in C–C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally.

The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in the formation of a complex containing a η3-tetraenyl ligand, resulting from the head-to-head C–C coupling between the alkyne functionalities of two conjugated enyne molecules Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 739, 1 September 2013, Pages 52–56
نویسندگان
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