کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1322712 | 977234 | 2010 | 9 صفحه PDF | دانلود رایگان |

Triorganotin chlorides Me3SnCl and (LNC)Me2SnCl (LNC = 2-[(dimethylamino)methyl]phenyl) reacted with potassium 1′-(diphenylphosphino)-1-ferrocenecarboxylate to give the respective carboxylates, Ph2PfcCO2SnMe3 (1) and Ph2PfcCO2SnMe2(LNC) (2; fc = ferrocene-1,1′-diyl), while the analogous triphenylstannyl derivative 3 resulted by condensation of Ph3SnOH with 1′-(diphenylphosphino)-1-ferrocenecarboxylic acid (Hdpf). Compounds 1 and 2 were smoothly oxidized with hydrogen peroxide or elemental sulfur to afford the corresponding P-chalcogen derivatives (P-oxides 1a and 2a; P-sulfides 1b and 2b). All compounds were characterized by multinuclear NMR, IR and mass spectroscopy, and the solid-state structures of 1, 1a, 2, 2a and 2b were determined by single-crystal X-ray diffraction. In the crystal structures of 1 and 1a, the tin atoms were found with distorted trigonal bipyramidal coordination environments completed by the CO or PO oxygens, respectively, from adjacent molecules, which in turn resulted in the formation of infinite linear assemblies. Tin atoms in 2, 2a, and 2b were found with trigonal bipyramidal surrounding as well, though with the donor substituent LNC assuming one of the axial donor sites. Compounds 2 and 2a crystallized as stoichiometric hydrates (2·1/2H2O, 2a·H2O), in which the water molecules served as hydrogen bond donors for the polar groups (CO and PO) and thus aided the formation of closed H-bonded assemblies; the structure of 2b was essentially molecular.
A series of triorganotin carboxylates [Fe(η5-C5H4P(E)Ph2)(η5-C5H4CO2SnR3)] (SnR3/E = SnMe3/void∗, SnMe3/O∗, SnMe3/S; SnPh3/void, SnMe2(LNC)/void∗, SnMe2(LNC)/O∗, and SnMe2(LNC)/S∗) have been prepared and characterized by spectroscopic methods. Crystal structures of five representatives (denoted with an asterisk) have been determined by X-ray crystallography, revealing a decisive influence of the substitution pattern at tin (LNC vs. simple substituents) and the nature of the phosphorus group (P vs. PO/PS) on the solid-state structures.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 2, 15 January 2010, Pages 271–279