کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1322714 | 977234 | 2010 | 6 صفحه PDF | دانلود رایگان |

2,2-Dimethyl- and 2-benzyl-2-methyl-1-(2,4,6-tri-tert-butylphenyl)-1-phosphaethenes were employed as ligand of mononuclear chlorogold(I) complexes, which catalyzed cycloisomerization of 1,6-enyne affording vinylcyclopentene exclusively in the absence of silver co-catalyst. The reaction mechanisms are discussed based on DFT calculations. In addition to the cycloisomerization, the phosphaalkene–chlorogold(I) complexes catalyzed cyclization of pent-4-ynoic acids providing γ-methylene-γ-lactones under basic conditions.
Mononuclear phosphaalkene–chlorogold(I) complexes [Mes∗PCRR′][AuCl] (R, R′ = Me, CH2Ph; Mes∗ = 2,4,6-tBu3C6H2) catalyzed cyclizations of 1,6-enynes and pent-4-ynoic acids affording vinylcyclopentenes and methylenelactones, respectively, in the absence of co-catalyst.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 2, 15 January 2010, Pages 291–296