Novel germylenes and stannylenes based on pyridine-containing dialcohol ligands

The reactions between M[N(SiMe3)2]2 (M = Ge, Sn) and three pyridine-based dialcohols yielded germylenes and stannylenes 1–6. The composition and structures of the novel compounds were established by elemental analyses, 1H and 13C NMR spectroscopy. The structures of insoluble species were confirmed by conversion to the corresponding dibromides 7–9. The single crystal structures of stannylene 4 and germylene 5 were determined by X-ray diffraction analyses. The germanium compound was found to be monomeric whilst the tin compound is a dimer. Both compounds possess strong transannular MN interaction in the solid phase.

The first representatives of a novel class of germylenes and stannylenes based on pyridine-containing dialcohols were prepared. The structures of two compounds (monomeric germylene and dimeric stannylene) were studied by X-ray analysis. In several cases the low-valent character of metallic centre was confirmed by the reaction with bromine.Figure optionsDownload as PowerPoint slide