کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1322842 1499835 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
CC reductive coupling mediated by attack at a spectator ligand
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
CC reductive coupling mediated by attack at a spectator ligand
چکیده انگلیسی


• Reductive coupling of bis(alkynyl) complex to a diyne complex.
• Solvent-mediated reaction involving attack at ancillary carbonyl ligand.
• Proposed mechanism supported by kinetic measurements and computational study.

The alkynyl ligands in the iridium(III) complex [Cp*Ir(CO)(CCPh)2] undergo reductive coupling to form the diyne complex [Cp*Ir(CO)(PhCCCCPh)]. This process is assisted by nucleophilic attack at the carbonyl ligand by the solvent.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 810, 15 May 2016, Pages 40–45
نویسندگان
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