کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1322870 | 977252 | 2009 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: One-pot three-component synthesis, structure and redox properties of ferrocenyl isoxazoles One-pot three-component synthesis, structure and redox properties of ferrocenyl isoxazoles](/preview/png/1322870.png)
A consecutive coupling-cycloaddition sequence of acid chlorides, terminal alkynes, and in situ generated nitrile oxides furnishes ferrocenyl substituted redox active isoxazoles in moderate to good yields. The structure was unambiguously assigned by X-ray structure analyses and the electronic structure was elucidated by computational methods. Redox potentials of all representatives are strongly effected by the electronic nature of the bridging isoxazoloyl moiety.
A consecutive coupling-cycloaddition sequence of acid chlorides, terminal alkynes, and in situ generated nitrile oxides furnishes ferrocenyl substituted redox active isoxazoles in moderate to good yields. Redox potentials of all representatives are strongly effected by the electronic nature of the bridging isoxazoloyl moiety.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 6, 15 March 2009, Pages 942–949