Dithiafulvenylphosphine as P- and P,S-ligand towards metal carbonyl fragments

The ability of the dithiafulvenylphosphine (P-DTF) to react as a monodentate (P) or a bidentate (P,S) ligand with metal carbonyl complexes such as Mo(CO)6 and MnBr(CO)5 allowed us to prepare a series of metal carbonyl complexes.