کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1323241 | 977275 | 2008 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Photoinduced iron–cyclopentadienyl (Fe–Cp) bond cleavage reactions and photocontrolled polymerizations of strained [1]ferrocenophanes Photoinduced iron–cyclopentadienyl (Fe–Cp) bond cleavage reactions and photocontrolled polymerizations of strained [1]ferrocenophanes](/preview/png/1323241.png)
Although extensive previous studies have shown that strained [1]ferrocenophanes predominantly undergo ring-opening chemistry at the bridging atom E–cyclopentadienyl (E–Cp) bond, recent reports have highlighted that reactivity at the Fe–Cp bond can also occur, especially on photoactivation. We provide an overview of recent results from our group and those of other researchers. In addition, the development of photocontrolled living polymerizations of sila[1]ferrocenophanes using Fe–Cp bond cleavage chemistry is described.
Extensive previous work has shown that strained [1]ferrocenophanes predominantly undergo ring-opening chemistry at the bridging atom E–Cp bond. Recent reports have highlighted that reactivity at the Fe–Cp bond can also occur, especially on photoactivation. We provide an overview of this new area of controlled Fe–Cp bond cleavage chemistry.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 5, 1 March 2008, Pages 802–807