کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1323282 | 977276 | 2015 | 8 صفحه PDF | دانلود رایگان |
• Reactions of 10-O(CH2CH2)2O-7,8-C2B9H11 with 1,2-S,S′/O,O′-nucleophiles were studied.
• New podands with pendant nido-carborane fragments were synthesized.
• 18C6 and 15C5 ethers with embedded cobalt bis(dicarbollide) fragment were prepared.
A series of podands (acyclic analogues of crown ethers) related to 18-crown-6 was obtained by ring-opening reactions of the 1,4-dioxane derivative of nido-carborane [10-O(CH2CH2)2O-7,8-C2B9H11] with 1,2-S,S′- and O,O′-dinucleophiles (1,2-dimercaptoethane, 1,2-dimercaptobenzene, 1,2-dimercapto-ortho-carborane, 1,2-dihydroxy-ortho-carborane). By stepwise ring-opening reactions of the dioxane derivative with sulfur-containing nucleophiles the podand related to 15-crown-5 was prepared as well. The reactions of the obtained podands with CoCl2 result in the macrocyclic ring closure giving the corresponding crown ethers with the incorporated cobalt bis(dicarbollide) fragment K[8,8′-μ-S(OCH2CH2OCH2CH2)2-3,3′-Co(1,2-C2B9H9)2] and K[8,8′-μ-o-C6H4(OCH2CH2OCH2CH2S)2-3,3′-Co(1,2-C2B9H9)2]. The structure of Na[8,8′-μ-o-C6H4(OCH2CH2OCH2CH2S)2-3,3′-Co(1,2-C2B9H9)2] was determined by single crystal X-ray diffraction.
A series of podands with pendant nido-carborane fragments was synthesized. The reactions of the podands with cobalt chloride produce the corresponding crown ethers with the incorporated cobalt bis(dicarbollide) fragment.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 798, Part 1, 1 December 2015, Pages 196–203