کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1323335 | 977280 | 2008 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, characterization and catalytic behaviour of ansa-zirconocene complexes containing tetraphenylcyclopentadienyl rings: X-ray crystal structures of [Zr{Me2Si(η5-C5Ph4)(η5-C5H3R)}Cl2] (R = H, But)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis, characterization and catalytic behaviour of ansa-zirconocene complexes containing tetraphenylcyclopentadienyl rings: X-ray crystal structures of [Zr{Me2Si(η5-C5Ph4)(η5-C5H3R)}Cl2] (R = H, But) Synthesis, characterization and catalytic behaviour of ansa-zirconocene complexes containing tetraphenylcyclopentadienyl rings: X-ray crystal structures of [Zr{Me2Si(η5-C5Ph4)(η5-C5H3R)}Cl2] (R = H, But)](/preview/png/1323335.png)
چکیده انگلیسی
The synthesis and structural characterization of the ansa-zirconocene complexes, [Zr{Me2Si(η5-C5Ph4)(η5-C5H3R)}Cl2] (R = H and But), are reported. They have been tested as catalysts in the polymerization and found to be inactive. In order to explain this, DFT calculations based on the transition states present in the polymerization process have been carried out.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 4, 15 February 2008, Pages 601-610
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 4, 15 February 2008, Pages 601-610
نویسندگان
Santiago Gómez-Ruiz, Dorian Polo-Cerón, Sanjiv Prashar, Mariano Fajardo, Vı´ctor L. Cruz, Javier Ramos, Evamarie Hey-Hawkins,