کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1323356 | 977280 | 2008 | 6 صفحه PDF | دانلود رایگان |
Optically active highly hindered half-sandwich ruthenium(II) compounds with C2-symmetric cyclopentadienyl ligands were synthesized from the ligand precursors, 4 and 5, which were derived from (−)-β-pinene. Thus, the reaction of the ligands with triruthenium dodecacarbonyl produced ruthenium compounds, 10 and 11, after oxidative treatment. These compounds were characterized by single crystal X-ray crystallography.
Optically active highly hindered half-sandwich ruthenium(II) compounds with C2-symmetric cyclopentadienyl ligands were synthesized from the ligand precursors, which were derived from (−)-β-pinene. Thus, the reaction of the ligands with triruthenium dodecacarbonyl produced ruthenium compounds, after oxidative treatment. These compounds were characterized by single crystal X-ray crystallography.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 4, 15 February 2008, Pages 781–786