کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1323464 | 977290 | 2007 | 5 صفحه PDF | دانلود رایگان |
Photochemical reactions of the dinitrogen complex Cp∗Re(CO)2N2 with tetrachloroethylene and trichloroethylene yield the coordination complexes Cp∗Re(CO)2(η2-tetrachloroethylene) (1) and Cp∗Re(CO)2(η2-trichloroethylene) (2), respectively. Complex 1 reacts thermally in polar organic solvents to produce the C–Cl bond activation product cis-Cp∗Re(CO)2(C2Cl3)Cl (3). All complexes were isolated and characterized by IR, 1H and 13C NMR spectroscopies and mass spectrometry. Complex 3 was also characterized by X-ray crystallography.
Photochemical reactions of Cp∗Re(CO)2N2 with tetrachloroethylene and trichloroethylene yield the coordination complexes Cp∗Re(CO)2(η2-C2Cl4) (1) and Cp∗Re(CO)2(η2-C2HCl3) (2), respectively. Complex 1 reacts thermally in polar organic solvents to produce the C–Cl bond activation product cis-Cp∗Re(CO)2(C2Cl3)Cl (3).Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 5, 1 February 2007, Pages 963–967