کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1323479 | 977290 | 2007 | 6 صفحه PDF | دانلود رایگان |
The reaction of the ylide carbethoxymethylenetriphenylphosphorane (EPPY), Ph3PCHCOOEt, with mercury (II) halides has been investigated. The resulting dimeric mercury (II)-ylide complexes are isostructural and of the form [(EPPY)(HgX2)]2 where X is either bromine (1), chlorine (2), or iodine (3). These complexes have been characterised by spectroscopic techniques and X-ray diffraction. The ylide ligands have been shown to be C-coordinated to the mercury (II) atom.
The reaction of the phosphorus ylide, carbethoxymethylenetriphenylphosphorane, Ph3PCHCOOEt, with a mercury (II) halide yields a dimeric complex of the form [(Ph3PCHCOOEt)(HgX2)]2 where X is either bromine, chlorine or iodine. These structures have been characterised fully using spectroscopic techniques and single-crystal X-ray diffraction.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 5, 1 February 2007, Pages 1081–1086