کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1323664 1499893 2013 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and serendipity in boron chemistry: A 50 year perspective
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and serendipity in boron chemistry: A 50 year perspective
چکیده انگلیسی


• Unexpected discoveries have played a major role in the history of science.
• Serendipitous findings have changed the direction of research and opened new areas.
• The interplay between planned synthesis and serendipity is illustrated by example.

Chance discovery is ubiquitous in the history of science, especially in areas where theory has tended to lag behind experimental findings. In fields such as organometallic and boron cluster chemistry, serendipity has been particularly important in opening new directions and shaping the evolution of these fields. In this article selected examples from the author's half century of research in borane, carborane, and metallaborane chemistry are used to illustrate the often intricate interplay between unexpected findings and targeted synthesis.

The graphical abstract illustrates one example of an unexpected finding cited in the paper, i.e., the oxidative fusion of two iron-bound carborane ligands to form tetracarbon carborane products.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 747, 1 December 2013, Pages 4–15
نویسندگان
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