کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1323665 1499893 2013 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Carbon insertion into borane clusters via nucleophilic addition reactions of borane and carborane anions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Carbon insertion into borane clusters via nucleophilic addition reactions of borane and carborane anions
چکیده انگلیسی


• General characteristics of nucleophilic addition reactions of cluster borane anions.
• Addition reactions of nido borane and carborane anions to multiple bonds in electrophilic substrates.
• Addition reactions of arachno borane and carborane anions to multiple bonds in electrophilic substrates.
• New approaches to the synthesis of carboranes and heterocarboranes.
• Mechanistic aspects of nucleophilic addition reactions.

New approaches to the synthesis of carboranes and heterocarboranes based on addition reactions of highly nucleophilic boron-cluster anions are briefly overviewed together with some mechanistic aspects. The anions, in which the negative charge is accumulated on the open face of the cage, become capable of coordinating to the most electrophilic center of the reacting substrate and are activated for addition reactions to multiply bonded substrates. Additions to cyanides, nitriles, isocyanides, aldehydes, and acyl chlorides lead usually to the insertion of one more carbon vertex into the boron framework, though the products may be in some cases unusual or unexpected. The methods based on nucleophilic addition have become an effective synthetic tool in the area of general carborane chemistry, though this specific field of cluster chemistry has still been far from being fully explored. One of the aims of this overview is to encourage a younger generation of chemists to return to building-up new borane clusters.

New approaches to the synthesis of carboranes and heterocarboranes based on addition reactions of highly nucleophilic boron-cluster anions to multiply bonded substrates are briefly overviewed.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 747, 1 December 2013, Pages 16–24
نویسندگان
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