کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1323812 | 1499896 | 2013 | 4 صفحه PDF | دانلود رایگان |
• 12-Membered ring is a missing link in borasiloxane ring systems.
• 1–3 are stable in solution, hence can be used in host guest chemistry.
• 1–3 can act as novel macrocyclic ligand systems to metal ions.
• Opens up new avenue in coordination chemistry as 1–3 can act as sensors to metals.
A one pot three component reaction of boric acid, diphenylsilanediol and functionalized alcoholic pyrazole in 1:1:1 stoichiometry using toluene as a solvent under reflux conditions afforded twelve-membered borasiloxane macrocycle [(Ph2Si)4(O)6(BR1PzR)2] {R1 = C6H4OH and R = H for 1, R1 = C6H4OH and R = CH3 for 2 R1 = C10H6OH and R = H for 3} in moderate yields. Single crystal X-ray elucidation revealed the formation of a puckered twelve-membered ring system. ESI-MS studies indicate the stability of these macrocyclic systems in solution.
A one pot three component reaction of boric acid, diphenylsilanediol and alcoholic pyrazole in 1:1:1 stoichiometry afforded twelve-membered borasiloxane macrocycle [(Ph2Si)4(O)6(BR1PzR)2] in moderate yields. Single crystal X-ray elucidation revealed the formation of puckered twelve-membered ring system. ESI-MS studies indicate the stability of these macrocyclic systems in solution.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 743, 15 October 2013, Pages 83–86