کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1323826 | 1499896 | 2013 | 5 صفحه PDF | دانلود رایگان |
• Neutral rhenium(I)-based mixed-ligands supramolecular coordination complexes.
• Self-assembly of Re(CO)3, anionic flexible donor, and neutral flexible donor.
• Bis(salicylaldehyde) as building unit for supramolecular coordination complex.
Neutral heteroleptic M2LL'-type supramolecular co-ordination complexes were synthesized in a one-step process using a tritopic fac-Re(CO)3 acceptor, dianionic flexible bis(chelating) oxygen donors, and neutral flexible bis(monodentate) nitrogen donors. Two flexible ligands and two fac-Re(CO)3 cores make up the cyclic framework. Complexes 1, and 2 were characterized by E.A., IR, UV-Vis spectroscopy and X-ray study.
Neutral heteroleptic M2LL'-type supramolecular co-ordination complexes were synthesized in a one-step process using a tritopic fac-Re(CO)3 acceptor, dianionic flexible bis(chelating) oxygen donors, and neutral flexible bis(monodentate) nitrogen donors.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 743, 15 October 2013, Pages 109–113