کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1323853 977307 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ferrocene bridged and substituted tetramethylcyclopentadienyl (or indenyl) carbonyl complexes of iron, ruthenium, and molybdenum
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Ferrocene bridged and substituted tetramethylcyclopentadienyl (or indenyl) carbonyl complexes of iron, ruthenium, and molybdenum
چکیده انگلیسی

Reactions of ferrocene bridged and substituted tetramethylcyclopentadiene ligands 1,1′-Fc(C5Me4H)2 (1) (Fc = 1,1′-ferrocenediyl) and (C5H5FeC5H4)C5Me4H (5) with Ru3(CO)12, Fe(CO)5, and Mo(CO)3(CH3CN)3 in refluxing xylene gave the corresponding trinuclear and tetranuclear complexes Fc[(C5Me4)M(CO)]2(μ-CO)]2 [M = Ru (2), Fe (3)], Fc[(C5Me4)Mo(CO)3]2 (4) and [(C5H5 FeC5H4)C5Me4M(CO)]2(μ-CO)2 [M = Ru (6), Fe (7)], [(C5H5FeC5H4)C5Me4Mo(CO)3]2 (8). Reactions of (3-indenyl)ferrocene (9) with Ru3(CO)12 or Fe(CO)5 in refluxing xylene or heptane, also gave the corresponding tetranuclear metal complexes [(C5H5FeC5H4)C9H6M(CO)]2(μ-CO)2 [M = Ru (10), Fe (11)]. The molecular structures of 2 and 3 were determined by X-ray diffraction analysis.

Reactions of ligands 1,1′-Fc(C5Me4H)2 and (C5H5FeC5H4)C5Me4H with Ru3(CO)12, Fe(CO)5, and Mo(CO)3(CH3CN)3 in refluxing xylene gave the corresponding bridged and substituted tetramethylcyclopentadienyl trinuclear and tetranuclear metal carbonyl complexes.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 11, 15 May 2006, Pages 2528–2533
نویسندگان
, , , ,