Synthesis and characterization of Ru(II) and Ir(III) complexes that bear camphoric 1,3-diamine ligands

• Five arene Ru(II) and Cp*Ir(III) complexes with d-camphor-derived ligands have been prepared.
• All the complexes were characterized using NMR and HRMS.
• Structures of one monosulfonamide 1,3-diamine and three complexes were confirmed by X-ray.

Two rigid N-monosulfonylated 1,3-diamine ligands have been prepared starting from commercially available d-camphor through three steps. Their reactions with [Ru(η6-arene)(μ-Cl)Cl]2 (arene = p-cymene or C6H5CO2Et) or [Ir(η5-C5Me5)(μ-Cl)Cl]2 afforded five new complexes. The structures of one monosulfonamide 1,3-diamine ligand and three organometallic complexes were confirmed by X-ray crystallography.

Two rigid N-monosulfonylated 1,3-diamine ligands have been synthesized from D-camphor. Their reactions with [Ru(η6-arene)(μ-Cl)Cl]2 (arene = p-cymene or C6H5CO2Et) or [Ir(η5-C5Me5)(μ-Cl)Cl]2 provided five new complexes. The structures of one monosulfonamide 1,3-diamine ligand and three organometallic complexes were confirmed by X-ray crystallography.Figure optionsDownload as PowerPoint slide