کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1323906 1499873 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of substituted titanocene dichloride derivatives by hydrosilylation
ترجمه فارسی عنوان
سنتز مشتقات تیتانوسن دی کلرید جایگزین توسط هیدروسیلیلاسیون
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی


• Titanium complexes bearing a Si–H group were modified by hydrosilylation.
• Mono-, bi- and tri-homonuclear two-component molecules were prepared.
• Between an organic and a metallic part of molecules is a changeable spacer.

Substituted titanocene complexes have been prepared by hydrosilylation of organic substrates containing a terminal double bond by cyclopentadienyl complexes of titanium bearing a Si–H functional group. This new synthetic protocol is demonstrated by synthesis of mono-, bi- and trihomonuclear complexes. The structures of prepared compounds have been characterized by standard methods (NMR, IR, and HRMS).

The series of novel substituted titanocene complexes have been prepared by hydrosilylation of organic substrates containing a terminal double bond by cyclopentadienyl complexes of titanium bearing a Si–H functional group. This new synthetic protocol is demonstrated by synthesis of mono-, bi- and tri-homonuclear complexes.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 768, 1 October 2014, Pages 115–120
نویسندگان
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