کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1323943 | 1499913 | 2013 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Aluminium complexes containing pyrazolyl–phenolate ligands as catalysts for ring opening polymerization of ε-caprolactone Aluminium complexes containing pyrazolyl–phenolate ligands as catalysts for ring opening polymerization of ε-caprolactone](/preview/png/1323943.png)
A series of pyrazolyl–phenolate ligand precursors has been described. Reactions of five pyrazolyl-phenolate ligand precursors, HOPhMePzMe, HOPhMePztBu, HOPhMePzPh, HOPhMePzF-Ph or HOPhHPztBu, with one molar equivalent of AlMe3 in THF gave the aluminium dimethyl complexes, Me2Al(OPhR1PzR2) [R1 = methyl, R2 = methyl, Me2Al(OPhMePzMe) (1); R1 = methyl, R2 = tert-butyl, Me2Al(OPhMePztBu) (2); R1 = methyl, R2 = phenyl, Me2Al(OPhMePzPh) (3); R1 = methyl, R2 = 4-fluorophenyl, Me2Al(OPhMePzF-Ph) (4); R1 = H, R2 = tert-butyl, Me2Al(OPhHPztBu) (5)], respectively. The molecular structures are reported for compounds 3 and 5. Their catalytic activities towards the ring opening polymerization reaction of ε-caprolactone in the presence of benzyl alcohol are also under investigation.
A series of pyrazolyl–phenolate ligand precursors has been described. Reactions of five ligand precursors with one molar equivalent of AlMe3 in THF gave the aluminium pyrazolyl–phenolate dimethyl complexes. Their catalytic activities towards the ring opening polymerization reaction of ε-caprolactone in the presence of benzyl alcohol are examined.Figure optionsDownload as PowerPoint slideHighlights
► Aluminium dimethyl complexes bearing pyrazolyl–phenolate ligands have been prepared.
► All complexes are active catalysts for the ROP of ε-caprolactone in the presence of benzyl alcohol.
► Bulkier substituent on the nitrogen atom of pyrazolyl ring could enhance the catalytic activities.
Journal: Journal of Organometallic Chemistry - Volume 725, 1 February 2013, Pages 15–21