کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1323978 | 1499877 | 2014 | 10 صفحه PDF | دانلود رایگان |
• Several acyclic ferrocene-based receptors 1–4 are synthesized in moderate yields.
• Receptors 1 and 2 are characterized by single-crystal X-ray diffraction analysis.
• Receptors 1–4 have selectivity for F− and HSO4− in the electrochemical behaviors.
• Receptors 1–4 have a good fluoride binding ability in DMSO-d6.
• The flexible receptors 1 and 2 can recognize fluoride ion excellent better.
Several novel acyclic multi-site receptors comprising of imidazolium moieties were synthesized and structurally characterized. All of these compounds were characterized through 1H NMR, 13C NMR, MS and IR, elemental analysis. The crystal structures of 1,4-bis(1-ferrocenylmethylimidazoliumylethoxy)-benzene hexafluorophosphate (1) and 1,3-bis(1-ferrocenylmethylimidazoliumylethoxy)-benzene hexafluorophosphate (2) were confirmed by X-ray crystallography, it was clear that molecules were linked by C–H⋯F hydrogen bonds interactions between PF6− and cations. The anion binding studies were investigated by electrochemistry and 1H NMR spectroscopy. Electrochemical behaviors indicated that all the receptors displayed unique electrochemical sensing property for F− in CH3CN. 1H NMR titrations demonstrated that all the receptors have good fluoride binding ability in DMSO-d6 through (C–H)+⋯X− hydrogen bonds. The flexible receptors 1 and 2 exhibited higher affinity toward anion than the rigid receptors 3 and 4.
The acyclic receptors comprising of ferrocenyl unit and imidazoliun moiety were synthesized and sructurally chracterized. The anion binding studies were investigated by electrochemistry and 1H NMR spectroscopy, which indicated that flexible receptors 1 and 2 exhibited higher affinity for fluoride ion.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volumes 763–764, 1 August 2014, Pages 34–43