کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1324014 | 977316 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
New chiral oxazoline based-rhodium(I) catalysts: Synthesis, characterisation, heterogeneisation and applications
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
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چکیده انگلیسی
New chiral oxazoline-based rhodium(I) homogeneous and heterogeneous catalysts have been prepared and fully characterised through 1H and 13C NMR, CP-MAS NMR and XPS. The method used for anchoring the catalyst onto silica was found particularly suitable, since the organometallic complexes remained unchanged over the procedure. The catalysts exhibited a moderate activity and enantioselectivity in hydrogenation of CO and CC double bond.
New chiral oxazoline-based rhodium(I) homogeneous and heterogeneous catalysts have been prepared, characterised and evaluated for enantioselective reduction of CO and CC double bonds, for which moderate activity and enantioselectivity were observed.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 4, 1 February 2006, Pages 741–747
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 4, 1 February 2006, Pages 741–747
نویسندگان
Nathalie Debono, Laurent Djakovitch, Catherine Pinel,