کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1324067 1499941 2010 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Asymmetric activation of dialkyl zirconocenes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Asymmetric activation of dialkyl zirconocenes
چکیده انگلیسی

Asymmetric alkylmethyl zirconocene derivatives were readily synthesised from Cp2ZrCl(CH3), and the appropriate alkyllithium reagent. The alkyl groups contain a silyl functionality on the β-position. These asymmetric dialkyl zirconocenes were successfully activated by B(C6F5)3, selectively abstracting the methyl group. The clear difference in the 13C NMR resonances, due to the alkyl groups on the cationic zirconocene made it possible to conclude that selective activation of this class of compounds was possible.

Asymmetric alkylmethyl zirconocene derivatives were readily synthesised from Cp2ZrCl(CH3), and the appropriate alkyllithium reagent. The alkyl groups contain a silyl functionality on the β-position. These asymmetric dialkyl zirconocenes were successfully activated by B(C6F5)3, selectively abstracting the methyl group. The clear difference in the 13C NMR resonances, due to the alkyl groups on the cationic zirconocene made it possible to conclude that selective activation of this class of compounds was possible.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 695, Issues 19–20, 1–15 September 2010, Pages 2277–2280
نویسندگان
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