کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1324093 | 977321 | 2005 | 6 صفحه PDF | دانلود رایگان |
Cross-coupling of vinyldisilacyclobutane with a variety of olefins in the presence of [RuH(Cl)(CO)(PCy3)2] leads to stereoselective formation of functionalized vinyldisilacyclobutanes. Analogous homo-coupling of vinyldisilacyclobutane leads to the formation of E- and gem-bis(silyl)ethenes. The reaction offers a new route for synthesis of attractive monomers for ring opening polymerization (ROP).
Silylative cross-coupling reaction of vinyldisilacyclobutane with a variety of olefins in the presence of [RuH(Cl)(CO)(PCy3)2] leads to highly stereoselective formation of functionalized organosilicon compounds - attractive monomers for ROP. However, the homo-coupling reaction of vinyldisilacyclobutane gives a mixture of E- and gem-bis(silyl)ethenes.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 20, 10 October 2005, Pages 4492–4497