کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1324243 | 977332 | 2010 | 6 صفحه PDF | دانلود رایگان |

Three new 3-D inorganic–organic polyoxovanadate-based coordination polymers [M2(bbi)(V2O6)2(H2O)2] [M = Co (1), Mn (2)] and [Ni2(bbi)3V4O12]·4H2O (3) (bbi = 1,1-(1,4-butanediyl)bis(imidazole)) have been synthesized under hydrothermal condition and characterized by elemental analyses, IR spectra, TG and single crystal X-ray diffraction. The 3-D networks of compounds 1 and 2 are constructed from neutral {M2V4O12} [M = Co (1), Mn (2)] layers that are pillared via the coordination of organic ligands bbi to M sites. Compound 3 is a 3-D eight-connected network, in which each binuclear [Ni2O4N6] node linked with other eight adjacent nodes through two {V4O12}4− clusters and six bbi ligands. The electrochemical behaviors of 1–3 modified carbon paste electrodes (1-CPE, 2-CPE and 3-CPE) in 1 M H2SO4 aqueous solution have been reported.
Three new 3-D inorganic–organic polyoxovanadate-based coordination polymers [M2(bbi)(V2O6)2(H2O)2] [M = Co (1), Mn (2)] and [Ni2(bbi)3V4O12]·4H2O (3) (bbi = 1,1-(1,4-butanediyl)bis(imidazole)) have been synthesized under hydrothermal condition and characterized by elemental analyses, IR, TG and single crystal X-ray diffraction. The electrochemical behaviors of 1–3 modified carbon paste electrodes have been studied.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 6, 15 March 2010, Pages 827–832