کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1324287 | 1499889 | 2014 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis of mixed-valence trinuclear carbonylmanganese dithiolates: Promoting vacant coordination sites in tricarbonyl[(1-5-η)-pentadienyl]manganese Synthesis of mixed-valence trinuclear carbonylmanganese dithiolates: Promoting vacant coordination sites in tricarbonyl[(1-5-η)-pentadienyl]manganese](/preview/png/1324287.png)
• Trinuclear mixed-valence paramagnetic manganese carbonyls with dithiolates were prepared.
• All three manganese centers in each complex present octahedral geometry. No metal–metal bonds were present.
• The complexes were prepared under mild conditions, in short reaction times, and in good yields.
• Sound characterization of the complexes by spectroscopic techniques and an X-ray analysis was achieved.
Mixed-valence complexes Mn3(CO)6(μ-S(CH2)nS-κ2-S,S′)3n = 2, 3, and 4 were prepared upon reaction of tricarbonyl[(1-5-η)-pentadienyl]manganese with the respective alkanedithiols at room temperature in good yields. The three metal centers are bound by thiolate bridges with no metal–metal bonds; one manganese atom exhibits a formal oxidation state of +4; while the other two possess an oxidation state of +1. EPR and X-ray analysis showed an octahedral environment around the manganese centers.
Mixed-valence complexes Mn3(CO)6(μ-S(CH2)nS-κ2-S,S′)3n = 2, 3, and 4 were prepared upon reaction of tricarbonyl[(1-5-η)-pentadienyl]manganese with the respective alkanedithiols. No metal–metal bonds exist in these trinuclear species; one manganese atom exhibits a formal oxidation state of +4; while the other two possess an oxidation state of +1.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 751, 1 February 2014, Pages 356–360