کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1324452 | 1499827 | 2016 | 7 صفحه PDF | دانلود رایگان |
• A N1CN2-Pd(II) non-symmetric pincer complex (2) was obtained in facile manner in good yields.
• The N1CN2-Pd(II) non-symmetric pincer complex (2) exhibited good catalytic activities in Suzuki–Miyaura Couplings.
• The structure of the non-symmetric pincer complex (2) was unequivocally determined by X-ray diffraction techniques.
The reflux reaction of ligand 3-[(2,4,6-trimethyl-phenylimino)-methyl]-phenol (1) with [Pd(NCPh)2Cl2] in toluene in presence of a base, results in the facile formation of the non-symmetric N1CN2Pd(II) pincer complex (2). The overall tandem reaction involves the benzonitrile activation at the nitrile moiety and a CH activation process at the aromatic ring of (1) providing a pincer compound with one six and one five membered palladacycles, this structure was unequivocally confirmed by single crystal X-ray diffraction analysis. Complex (2) was used in Suzuki–Miyaura couplings demonstrating this compound to be an efficient catalyst for these transformations.
The tandem process involving benzonitrile activation of [Pd(NCPh)2Cl2] and a CH activation process at the aromatic ring of the ligand 3-[(2,4,6-trimethyl-phenylimino)-methyl]-phenol (1) leads to the facile formation of the non-symmetric N1CN2Pd(II) pincer complex (2). The structure of this compound was unequivocally determined by single crystal X-ray diffraction analysis, exhibiting a pincer motif with one six (imidic ester) and one five (imine) membered palladacycles with the Pd(II) center located into a slightly distorted square planar environment. Complex (2) was proved to be an efficient catalyst for Suzuki–Miyaura couplings.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 819, 15 September 2016, Pages 69–75