کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1324455 1499827 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural characterization, vibrational studies and optical properties of a new luminescent organic-inorganic material [C6H20N3]BiI6·H2O
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Structural characterization, vibrational studies and optical properties of a new luminescent organic-inorganic material [C6H20N3]BiI6·H2O
چکیده انگلیسی


• Crystal structure of a new zero dimensional compounds (C6H20N3)BiI6·H2O.
• Vibrational properties were studied by Raman scattering and infrared spectroscopy.
• Optical absorption and photoluminescence properties in the visible region.

The (C6H20N3)BiI6·H2O compound is a new crystal belonging to the large hybrid organic-inorganic compounds family, which has been synthesized by the solvent evaporation method and characterized by single crystal X-ray diffraction at room. It crystallizes in the zero-dimensional (0-D) triclinic P  1¯ space group. The cell dimensions are: a = 8.572 (5) Å, b = 11.838 (5) Å, c = 12.707 (5) Å, α = 74.317 (5)°, β = 71.043 (5)° and γ = 71.419 (5)°. The crystal structure consists of a discrete ionic layer of bis(3-azaniumylpropyl)azanium cations, hexa-iodobismuthate anions and neutral water molecules linked via simple and bifurcated NH⋯I(OW) and O(W)H⋯I hydrogen bonds. The structure of the prepared compound has been investigated using the group theory and IR and Raman spectroscopic techniques. The detailed interpretation of the vibrational modes was carried out. The optical absorption measurements on a (C6H20N3)BiI6·H2O pellet have revealed two absorption bands at 2.27 and 2.78 eV. In the end, two room temperature photoluminescence emissions attributed to the excitonic transition in the [BiI6]3− anions, were observed in the red spectral range at energy values of 1.87 and 2.05 eV.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 819, 15 September 2016, Pages 95–102
نویسندگان
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