کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1324678 | 1499946 | 2009 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Adduct formation of [(η7-C7H7)Hf(η5-C5H5)] with isocyanides, phosphines and N-heterocyclic carbenes: An experimental and theoretical study Adduct formation of [(η7-C7H7)Hf(η5-C5H5)] with isocyanides, phosphines and N-heterocyclic carbenes: An experimental and theoretical study](/preview/png/1324678.png)
The reactions of [(η7-C7H7)Hf(η5-C5H5)] (1b) with the two-electron donor ligands tert-butyl isocyanide (tBuNC), 2,6-dimethylphenyl isocyanide (XyNC), 1,3,4,5-tetramethylimidazolin-2-ylidene (IMe) and trimethylphosphine (PMe3) are reported. The 1:1 complexes [(η7-C7H7)Hf(η5-C5H5)L] (2b, L = tBuNC; 3b, L = XyNC; 4b, L = IMe, 5b, L = PMe3) have been isolated in crystalline form, and their molecular structures have been determined by X-ray diffraction analyses. The stabilities of these hafnium complexes were probed via spectroscopic and theoretical methods, and the results were compared to those previously reported for the corresponding zirconium complexes derived from [(η7-C7H7)Zr(η5-C5H5)] (1a). The X-ray crystal structure of the PMe3 adduct [(η7-C7H7)Zr(η5-C5H5)(PMe3)] (5a) was also established.
The reactivity of the sandwich compound [(η7-C7H7)Hf(η5-C5H5)] (trohafcene) towards the two-electron donor ligands tert-butyl isocyanide (tBuNC), 2,6-dimethylphenyl isocyanide (XyNC), 1,3,4,5-tetramethylimidazolin-2-ylidene (IMe) and trimethylphosphine (PMe3) has been studied, and the stabilities of the resulting 1:1 adducts were probed via spectroscopic and theoretical methods.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issues 7–8, 1 April 2009, Pages 1244–1250