کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1324714 1499921 2012 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A push–pull azobenzene is mercurated twice at the ring with less electron density
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A push–pull azobenzene is mercurated twice at the ring with less electron density
چکیده انگلیسی

Treatment of N,N-dialkyl-4-[4-nitrophenyl)diazenyl] anilines with a mercury(II) salt in anhydrous trifluoroacetic acid results in single and double metallation of the ring with less electron density. The seemingly counterintuitive outcome of the reaction was rationalized through experimental and computational investigations of the reaction mechanism.

Experimental and computational investigations identified kinetic control of the process as the likely explanation for such a counterintuitive result. Figure optionsDownload as PowerPoint slideHighlights
► Reaction of push–pull azodyes with mercury (II) salts.
► Metallation of the ring with less electron density.
► Kinetically controlled process.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 716, 1 October 2012, Pages 11–18
نویسندگان
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