Structure effect of TsDPEN derivatives on enantioselectivity of asymmetric transfer hydrogenation

TsDPEN derivative (3,3′,5,5′-TMTsDPEN) was synthesized and applied in asymmetric transfer hydrogenation of ketones. The influence of chiral ligands’ NCCN dihedral angles to the enantioselectivities of the reaction was discussed.

TsDPEN derivative (3,3′,5,5′-TM TsDPEN) was synthesized and applied in asymmetric transfer hydrogenation of ketones. The influence of chiral ligands’ NCCN dihedral angles to the enantioselectivities of the reaction was discussed.Figure optionsDownload as PowerPoint slide