کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1325190 977373 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
GaCl3-assisted [3+2] cycloaddition: A route to new binary PN-heterocycles
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
GaCl3-assisted [3+2] cycloaddition: A route to new binary PN-heterocycles
چکیده انگلیسی

Starting from a [3+2] synthetic tool kit, new PN-heterocycles may be isolated according to a new synthetic approach called GaCl3-assisted [3+2] cycloaddition. According to this concept the dipolarophile Mes∗–NP–Cl (Mes∗ = 2,4,6-tri-tert-butylphenyl) was reacted with the 1,3-dipole (TMS)2N–N(TMS)–PCl2 (TMS = trimethylsilyl) yielding the kinetically stabilized [3+2] cycloaddition product triazadiphosphole, Mes∗N3P2, stabilized as GaCl3 adduct. Synthesis, structure and bonding are discussed.

Starting from a [3+2] synthetic tool kit, a new triazadiphosphole has been isolated and fully characterized in a new synthetic approach called GaCl3-assisted [3+2] cycloaddition.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 13, 1 June 2007, Pages 2839–2842
نویسندگان
, , ,