کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325190 | 977373 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
GaCl3-assisted [3+2] cycloaddition: A route to new binary PN-heterocycles
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: GaCl3-assisted [3+2] cycloaddition: A route to new binary PN-heterocycles GaCl3-assisted [3+2] cycloaddition: A route to new binary PN-heterocycles](/preview/png/1325190.png)
چکیده انگلیسی
Starting from a [3+2] synthetic tool kit, new PN-heterocycles may be isolated according to a new synthetic approach called GaCl3-assisted [3+2] cycloaddition. According to this concept the dipolarophile Mes∗–NP–Cl (Mes∗ = 2,4,6-tri-tert-butylphenyl) was reacted with the 1,3-dipole (TMS)2N–N(TMS)–PCl2 (TMS = trimethylsilyl) yielding the kinetically stabilized [3+2] cycloaddition product triazadiphosphole, Mes∗N3P2, stabilized as GaCl3 adduct. Synthesis, structure and bonding are discussed.
Starting from a [3+2] synthetic tool kit, a new triazadiphosphole has been isolated and fully characterized in a new synthetic approach called GaCl3-assisted [3+2] cycloaddition.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 13, 1 June 2007, Pages 2839–2842
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 13, 1 June 2007, Pages 2839–2842
نویسندگان
Peter Mayer, Axel Schulz, Alexander Villinger,