کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325290 | 977377 | 2007 | 10 صفحه PDF | دانلود رایگان |

The oxidative electrochemistry of 11 chiral bis-phosphinoferrocene ligands, all within the Josiphos class of ligands, was examined in methylene chloride. The oxidation of these ligands displays multiple waves of varying chemical reversibility. Palladium(II) and platinum(II) complexes with the general formula [MCl2(P–P)] (M = Pd or Pt; P–P = Josiphos) were prepared, characterized by NMR and cyclic voltammetry. The electrochemistry simplifies greatly upon coordination of the Josiphos ligands. The X-ray structures of a palladium(II) and platinum(II) complex of the same Josiphos ligand are reported.
The oxidative electrochemistry of 11 chiral bis-phosphinoferrocene ligands, all within the Josiphos class of ligands, was examined in methylene chloride. In addition, palladium(II) and palatinum(II) complexes with the general formula [MCl2(P–P)] (M = Pd or Pt; P–P = Josiphos) were prepared, characterized by NMR and cyclic voltammetry and the X-ray structures of two complexes reported.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 12, 15 May 2007, Pages 2365–2374